Rubidium

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The image of an ‘electric eye’ is inspired by the use of rubidium in photocells (sensors that detect light).

Fact Box

Density 1.53
Melting Point 39.30°C
Boiling Point 688°C

Uses

Rubidium is little used outside research. It has been used as a component of photocells, to remove traces of oxygen from vacuum tubes and to make special types of glass.

It is easily ionised so was considered for use in ion engines, but was found to be less effective than caesium. It has also been proposed for use as a working fluid for vapour turbines and in thermoelectric generators.

Rubidium nitrate is sometimes used in fireworks to give them a purple colour.

History

The lithium potassium mineral lepidolite was discovered in the 1760s and it behaved oddly. When thrown on to glowing coals it frothed and then hardened like glass. Analysis showed it to contain lithium and potassium, but it held a secret: rubidium.

In 1861, Robert Bunsen and Gustav Kirchhoff, of the University of Heidelberg, dissolved the ore in acid and then precipitated the potassium it contained which carried down another heavier alkali metal. By carefully washing this precipitate with boiling water they removed the more soluble potassium component and then confirmed that they really had a new element by examining the atomic spectrum of what remained. This showed two intense ruby red lines never seen before, indicating a new element, which they named after this colour.