Silicon

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The image is based on a diatom. Diatoms are photosynthesising algae. They are unique in that their cell walls are made of silica (hydrated silicon dioxide).

Fact Box

Density 2.3296
Melting Point 1414°C
Boiling Point 3265°C

Uses

Silicon is one of the most useful elements to mankind. Most is used to make alloys including aluminium-silicon and ferro-silicon (iron-silicon). These are used to make dynamo and transformer plates, engine blocks, cylinder heads and machine tools and to deoxidise steel.

Silicon is also used to make silicones. These are silicon-oxygen polymers with methyl groups attached. Silicone oil is a lubricant and is added to some cosmetics and hair conditioners. Silicone rubber is used as a waterproof sealant in bathrooms and around windows, pipes and roofs.

The element silicon is used extensively as a semiconductor in solid-state devices in the computer and microelectronics industries. For this, hyperpure silicon is needed. The silicon is selectively doped with tiny amounts of boron, gallium, phosphorus or arsenic to control its electrical properties.

Granite and most other rocks are complex silicates, and these are used for civil engineering projects. Sand (silicon dioxide or silica) and clay (aluminium silicate) are used to make concrete and cement. Sand is also the principal ingredient of glass, which has thousands of uses. Silicon, as silicate, is present in pottery, enamels and high-temperature ceramics.

Silicon carbides are important abrasives and are also used in lasers.

History

Silica (SiO2) in the form of sharp flints were among the first tools made by humans. The ancient civilizations used other forms of silica such as rock crystal, and knew how to turn sand into glass. Considering silicon’s abundance, it is somewhat surprising that it aroused little curiosity among early chemists.

Attempts to reduce silica to its components by electrolysis had failed. In 1811, Joseph Gay Lussac and Louis Jacques Thénard reacted silicon tetrachloride with potassium metal and produced some very impure form of silicon. The credit for discovering silicon really goes to the Swedish chemist Jöns Jacob Berzelius of Stockholm who, in 1824, obtained silicon by heating potassium fluorosilicate with potassium. The product was contaminated with potassium silicide, but he removed this by stirring it with water, with which it reacts, and thereby obtained relatively pure silicon powder.